dc.contributor.author | Bilgin, Ahmet | |
dc.contributor.author | Yanmaz, Durmus | |
dc.contributor.author | Yagci, Cigdem | |
dc.date.accessioned | 2020-11-20T16:18:27Z | |
dc.date.available | 2020-11-20T16:18:27Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 1300-0527 | |
dc.identifier.uri | https://doi.org/10.3906/kim-1407-15 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12809/3573 | |
dc.description | Bilgin, Ahmet/0000-0003-3351-5185 | en_US |
dc.description | WOS: 000345559800017 | en_US |
dc.description.abstract | New polymeric phthalocyanine moieties (M = 2H, Zn, Ni, Cu, and Co) were synthesized via polytetracyclomerization reaction of o-bis[3-(3,4-dicyanophenoxy) propyloxy]benzene (3), which can be obtained by the reaction of 4-nitrophthalonitrile with o-bis[(3-hydroxypropyl)oxy]benzene. Aggregation and disaggregation behavior of the polymeric phthalocyanine (5) was studied with some alkali and earth alkali metal cations. Measured intrinsic viscosities of the polymeric phthalocyanines exhibited a substantial decreasing tendency with dilution of the solution. Thermogravimetric analysis was performed under air by using DSC and DTG/TGA techniques and indicated that these polymers have good thermal stability. AC and DC electrical conductivities of the polymeric phthalocyanines were investigated in the frequency range 100 Hz-1 MHz within the temperature range 298-343 K. AC/DC conductivities of the samples were found to be between 10 (5) and 10 (7) S cm (1) at ambient temperature under argon atmosphere. The structures of new synthesized compounds were characterized by using microanalysis; various spectroscopic methods such as UV-Vis, FT-IR, H-1 NMR, and C-13 NMR spectroscopy; and MS spectra. | en_US |
dc.description.sponsorship | Kocaeli University Scientific Research Projects UnitKocaeli University [BAP-2010/38] | en_US |
dc.description.sponsorship | Financial support from Kocaeli University Scientific Research Projects Unit (Project number BAP-2010/38) is acknowledged. We wish to thank Assoc Prof Dr Muhammet Isiklan (Kirikkale University) for his assistance with the elemental analysis, and DSC and TGA measurements. | en_US |
dc.item-language.iso | eng | en_US |
dc.publisher | Scientific Technical Research Council Turkey-Tubitak | en_US |
dc.item-rights | info:eu-repo/semantics/openAccess | en_US |
dc.subject | Polymeric Phthalocyanine | en_US |
dc.subject | Metallophthalocyanines | en_US |
dc.subject | Aggregation | en_US |
dc.subject | AC/DC Electrical Conductivities | en_US |
dc.subject | Thermal Properties | en_US |
dc.subject | DSC/TGA | en_US |
dc.title | Synthesis and properties of novel polymeric metal-free and metallophthalocyanines containing peripherally long 1,2-bis[(3-oxapropyl)oxa]benzene derivatives | en_US |
dc.item-type | article | en_US |
dc.contributor.department | MÜ | en_US |
dc.contributor.departmentTemp | [Bilgin, Ahmet; Yagci, Cigdem] Kocaeli Univ, Dept Sci Educ, Kocaeli, Turkey -- [Yanmaz, Durmus] Mugla Sitki Kocman Univ, Dept Sci Educ, Kotekli, Mugla, Turkey | en_US |
dc.identifier.doi | 10.3906/kim-1407-15 | |
dc.identifier.volume | 38 | en_US |
dc.identifier.issue | 6 | en_US |
dc.identifier.startpage | 1135 | en_US |
dc.identifier.endpage | 1152 | en_US |
dc.relation.journal | Turkish Journal of Chemistry | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |