Synthesis and spectroscopic studies of copper(II) and nickel(II) complexes containing hydrazonic ligands and heterocyclic coligand

Abstract

Two types of copper(II) and nickel(II) complexes derived from benzophenone anthranoylhydrazone (L-1), 2-acetonaftanone anthranoylhydrazone (L-2), 4-phenylacetonaftonone anthranoylhydrazone (LA benzophenone salicyoylhydrazone (L-4), 2-acetonaftanon salicyoylhydrazone (L-5), 4-phenylacetonaftanon salicyoylhydrazone (L-6) and bidentate heterocyclic base [1,10-phenanthroline (phen)] with general stoichiometry [ML2] and [ML(phen)]Cl have been synthesized and characterized by elemental analysis, infrared spectra, UV-vis electronic absorption spectra and magnetic susceptibility measurements. The effect of varying pH and solvent on the absorption behavior of both ligands and complexes have been investigated. According to the IR spectra, the ligands act as monobasic bidentate and coordination takes place in the enol tautomeric form. (c) 2005 Elsevier B.V. All rights reserved.